Al Bell (tracks: A1, B1, B4, B3), Al Jackson, Jr. (tracks: A2, A4, A5, B3), Jim Stewart (tracks: A2, A4), Jo Hutchinson (tracks: A3, B2), Marvell Thomas (tracks: A1, B1, B4), Pervis Staples (tracks: A3, A5), William C. Brown III (tracks: A1, B1, B4)
Andrew Hamilton of AllMusic wrote retrospectively: "Sunshine has some excellent cuts and some that don't quite fit the Chicagoans' style."[2] John Storm Roberts of High Fidelity wrote: "Fantasy Records has begun reissuing some of the old Stax catalog, and "Sunshine" is part of that venture-a bunch of singles backed by Stax house musicians, none of them previously released on albums. The result is pure and amazingly cohesive joy. Without once departing from the classic framework of female group rhythm & blues, "Sunshine" is as rich and varied as anything I've heard in months. With only one exception, Any Way You Look at It, every number positively drips with tasty touches in arrangement, singing. and playing."[5] With a 3.5 out of 5 stars rating John Shearlaw of Record Mirror exclaimed "Old Emotions, new Emotions-they're just as good."[3]Phyl Garland of Stereo Review commented: "Sunshine sounds amazingly fresh. Vocal artistry prevails over background effects as the Emotions weave their way in and out of cool, melodious songs."[6]